Friday, January 23, 2009

Powder

A powder is a dry, bulk solid composed of a large number of very fine particles that may flow freely when shaken or tilted. Powders are a special sub-class of granular materials, although the terms powder and granular are sometimes used to distinguish separate classes of material. In particular, powders refer to those granular materials that have the finer grain sizes, and that therefore have a greater tendency to form clumps when flowing. Granulars refers to the coarser granular materials that do not tend to form clumps except when wet.

Typically, a powder can be compacted or loosened into a vastly larger range of bulk densities than can a coarser granular material. When deposited by sprinkling, a powder may be very light and fluffy. When vibrated or compressed it may become very dense and even lose its ability to flow. The bulk density of coarse sand, on the other hand, does not vary over an appreciable range. The clumping behavior of a powder arises because of the molecular Van der Waals force that causes individual grains to cling to one another. Actually, this force is present not just in powders, but in sand and gravel, too. However, in such coarse granular materials the weight and the inertia of the individual grains are much larger than the very weak Van der Waals forces, and therefore the tiny clinging between grains does not have a dominant effect on the bulk behavior of the material. Only when the grains are very small and lightweight does the Van der Waals force become predominant, causing the material clump like a powder.

Many other powder behaviors are common to all granular materials. These include segregation, stratification, jamming and unjamming, fragility, loss of kinetic energy, frictional shearing, compaction and Reynolds' dilatancy. Powders are transported in the atmosphere differently than a coarse granular material. For one thing, tiny particles have relatively little inertia compared to the drag force of the gas that surrounds them, and so they tend to go with the flow instead of traveling in straight lines. For this reason, powders may be an inhalation hazard. 

Larger particles cannot weave through the body's defenses in the nose and sinus, but will strike and stick to the mucous membranes. The body then moves the mucous out of the body to expel the particles. The smaller particles on the other hand can travel all the way to the lungs from which they cannot be expelled. Serious and sometimes fatal diseases such as silicosis are a result from working with certain powders without adequate respiratory protection.

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